Atmospheric Mercury Measurements up and Running!
Onboard the CCGS Amundsen I am studying atmospheric mercury and its deposition to the marine environment. After many laborious weeks setting up and testing equipment we have finally begun to produce accurate measurements of mercury in the atmosphere. Working in such a harsh environment provides a unique challenge, and problems have become very familiar when trying to install sensitive measurement equipment in -35oC temperatures. It seems as if we’ve encountered every hurdle imaginable along the way including broken glassware, the inability to maintain operating temperatures, and instruments that enjoy burning our heated boots. On top of all the equipment and environment problems comes the usual plethora of broken spirits and frozen fingers, however with the help from the ship crew and hard-working colleagues back in Winnipeg, all problems have been resolved and the science has prevailed.

In Arctic regions mercury is subjected to a
unique savaging process known as
Atmospheric Mercury Depletion Events, or
AMDE’s. During these events chemical
reactions involving low level ozone, light,
frozen surfaces, and halogen radicals such
as bromine act to convert the common
un-reactive gaseous mercury to a highly
reactive form. This reactive mercury
species can then be easily deposited onto
the snow, ice, or ocean surface. AMDE’s
typically make their appearance at the
beginning of polar sunrise in early
February and continue until snow melt in
mid June.

Mercury is known as a global pollutant due
to its high toxicity, its ability to be
transported over large distances, and its
ability to biomagnify along the food chain.
Average global concentrations of
atmospheric mercury have remained fairly
constant over the last 10 years, however
despite this mercury levels in arctic
mammals has been increasing. The aim of my
study is to identify the intensity of these
events, as well as determine their
contribution to mercury loading in the
marine environment. The circumpolar flaw
lead system provides a unique of study in
that the formed open water provides a major
source for halogen radicals required which
may intensify the AMDE’s leading to
increased deposition, and in turn increased
contamination. The open water also provides
an area where the deposited mercury can
directly enter the marine environment. With
global warming, open water associated with
these flaw leads may be increasing in size
leading to increased deposition of mercury
compared to previous years. I hope that
this study will help shed new light on the
mystery of increasing arctic mercury
contamination.
Jeff.
